Successfully complete the game with all the league and cups under the hard difficulty setting. The European All-Star Team, World All-Star Team, Classic European All-Star Team, and Classic World All-Star Team will be unlocked.
To Unlock World and European Classic AllStar
Go to Master League,choose any team,set the difficulty to Normal with 10 minutes to play.Now play and make sure to stay at the top of the league after the 14 match( does'nt matter if you have lose record or draw ) just make sure finish first of top.After the credits,the memory cards also will autosave at the screen to confirm that the classic AllStar is playable at the exhibiton modes.
Unlock Secret World & European All Star
Go to international Cup,choose any team,set difficulty to normal with 10 minutes,and play till win the cup.After the credits,it will autosave the memory card to tell you that two new Team is Playable.Later check it out at the exhibition modes.(choose autosave)